碳羟磷灰石对废水中铅离子吸附研究
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P619.259 X703

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863项目(2004AA649370);国家杰出青年科学基金项目(50425927、50225926);衡阳师范学院青年基金项目(2005A02).


Study on the Adsorption of Pb2+ in Wastewater by Carbonate Hydroxyapatite
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    摘要:

    利用废弃蛋壳制备碳羟磷灰石(简称CHAP),并用作去除废水中Pb^2+的吸附剂。考查了pH值、吸附时间、温度、吸附剂用量以及Pb^2+初始浓度等因素对吸附效果的影响。结果表明:0.6g/L的CHAP对750mg/L的Pb^2+的去除率高达99.9%,吸附容量达到1243.75mg/g。CHAP对Pb^2+吸附的吸附等温线均符合Freundlich和Langmuir两种模式,从Freundlich方程中的常数1/n=0.0184可知,该吸附反应为吸热自发反应,且反应速率快。

    Abstract:

    Carbonate hydroxylapatite(CHAP),prepared from abandoned eggshell,was used to remove Pb2+ from simulated wastewater.The factors that might influent the adsorption performance of CHAP were investigated,such as pH values,adsorption time,reaction temperature,CHAP dosage and the initial concentration of Pb2+.The results showed that when CHAP dosage was 0.6g/L and initial concentration of Pb2+ was at 750 mg/L,the removal ratio of Pb2+ by CHAP adsorption could reach up to 99.9%,and the adsorption capacity was up to1243.75 mg/g.The adsorption isotherms for Pb2+could be well fitted by both Freundlich and Langmuir equation.According to the constant the 1/n=0.0184 in the Freundlich equation,a conclusion could be made that the adsorption reaction was an easily spontaneous endothermic process with high reaction rate.

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唐文清 曾荣英 高帅 曾光明 李小明 陈朝猛.碳羟磷灰石对废水中铅离子吸附研究[J].矿业研究与开发,2007,(2):35-38,50

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  • 收稿日期:2006-05-08
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