基于黄原胶的复合型抑尘剂制备及特性研究
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湖南科技大学

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X936

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湖南省自然科学基金青年项目


Preparation and characterization study of composite dust suppressant based on xanthan gum
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1.Hunan University of Science &2.Technology

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    摘要:

    为减少矿场中无组织排放的细颗粒物进入大气,避免其对人体健康、生产安全和大气环境造成严重危害,提出制备一种以黄原胶为团聚剂的复合型抑尘剂。选择阴离子表面活性剂SDS、SDBS以及非离子表面活性剂OP-10(烷基酚聚氧乙烯醚)、吐温-20、吐温-80,并与0.05%XTG(黄原胶)作为团聚剂进行复配,通过表面张力、接触角和沉降实验,发现OP-10对0.05%XTG溶液润湿性的改善效果最为明显,鉴于经济因素,最终选择0.05%OP-10+0.05%XTG(命名为M-OX)作为最佳抑尘剂配方;同时,设计对照组,通过pH、保水性、宏微观形貌分析和抗风蚀实验研究了M-OX的特性,并揭示了M-OX的抑尘机理。结果表明:M-OX的pH为8.03,对机器和环境等不会造成严重影响;常温下,M-OX前期的保水性较差,但随着水分的蒸发,其保水性逐渐大于0.05%OP-10和水;从宏观角度看,喷洒M-OX的焦煤表面干燥后比喷洒水和0.05%XTG更光滑,裂纹更少。相对于喷洒0.05%OP-10,裂纹也更少;从微观角度看,喷洒水和0.05%OP-10的两种煤样干燥后,其形貌与原煤样相比无太大差别。而喷洒0.05%XTG和M-OX的两种煤样的粒径较大,其中喷洒M-OX的最大;喷洒M-OX的两种煤样干燥后的抗风蚀能力最强。因此,这种复合型抑尘剂具有绿色环保的特性,抑尘效果显著。

    Abstract:

    To mitigate the unorganized emission of fine particulate matter into the atmosphere from mining operations, which poses significant risks to human health, production safety, and the atmospheric environment, a novel dust suppressant composed of xanthan gum as an agglomerating agent is proposed. This formulation incorporates anionic surfactants SDS, SDBS, and nonionic surfactants OP-10 (alkylphenol polyoxyethylene ether), Tween-20, and Tween-80, combined with 0.05% XTG (xanthan gum) as the agglomerating agent. Through experiments on surface tension, contact angle, and sedimentation, it was found that OP-10 significantly improves the wettability of the 0.05% XTG solution. Considering economic factors, 0.05% OP-10 + 0.05% XTG (named M-OX) was selected as the optimal dust suppressant formula. Additionally, control group experiments were conducted to study the characteristics of M-OX through pH, water retention, macroscopic and microscopic morphology analysis, and wind erosion resistance tests, revealing the dust suppression mechanism of M-OX. The results indicate that M-OX has a pH of 8.03, posing no severe impact on machinery or the environment. At room temperature, M-OX initially shows poor water retention, but as water evaporates, its water retention gradually surpasses that of 0.05% OP-10 and water. Macroscopically, surfaces treated with M-OX are smoother and exhibit fewer cracks compared to those treated with water or 0.05% XTG. Microscopically, coal samples treated with water and 0.05% OP-10 show no significant morphological differences from untreated samples, whereas those treated with 0.05% XTG and M-OX have larger particle sizes, with M-OX-treated samples being the largest. The wind erosion resistance of coal samples treated with M-OX is the strongest. Thus, this composite dust suppressant showcases environmentally friendly characteristics and significant dust suppression efficacy.

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  • 收稿日期:2024-03-01
  • 最后修改日期:2024-04-01
  • 录用日期:2024-04-18
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